Overcoming the effective medium limitations on thermoelectric composites
By: Michael Adams
Time: 11:30am – noon
Abstract: Composites of semiconductors are often considered as a way to yield high thermoelectric figures of merit. The most constraining limitation in this approach is given by the effective medium theory [1,2]. When one considers a composite made from two thermoelectric materials, A and B, in the absence of interactions between them the thermoelectric figure of merit of the composite cannot exceed that of the highest of the figures of merit of either A or B [1]. However, it is possible for thermoelectric power factor of the composite to exceed the highest of the power factors of either A or B [2]. Here we describe a mechanism that can lift this limitation by treating charge and heat flux differently. Silica beads coated with a conducting shell are inserted into a thermoelectric host. Phonons are scattered by the beads but electrons can pass through the conducting shells. In this talk, we will present the theory first, followed by experimental data demonstrating enhancement of ZT in p-type (Bi,Sb)2Te3 for room temperature operation.
Electric Field Vector Measurements in an AC Dielectric Barrier Discharge Overlapped with a Nanosecond Pulse Discharge
By Ben Goldberg
Time: 12:10 – 12:45pm
Time-resolved electric field measurements by picosecond CARS / 4-wave mixing are carried out in a double dielectric barrier discharge in H2 between two plane electrodes covered by quartz plates. The discharge is sustained by an AC voltage waveform, overlapped with nanosecond pulses (peak voltage 9 kV, pulse FWHM 100 ns), generated when the AC voltage is zero and operated at twice the frequency. Measurements taken in the AC discharge without nanosecond pulses show that electric field remains nearly constant during the majority AC discharge period. However, adding nanosecond pulses to the AC waveform results in large-volume breakdown generated every half-period, with a well-reproduced time delay after each pulse. Each of these “regular” AC breakdowns results in significant electric field reduction in the discharge volume. Basically, diffuse plasma produced by a nanosecond pulse neutralizes surface charge accumulated during the AC discharge and generates nearly uniform volume ionization, which results in subsequent large-volume breakdown when the AC voltage is applied. Thus, the results show that combining the AC waveform with nanosecond pulses transforms the AC discharge from a superposition of random, small scale micro-discharges to regular, large volume discharges.
Bio: Ben Goldberg received his B.S. in physics from Ohio State University as well as his M.S. in Mechanical Engineering. Currently, he is working for Dr. Adamovich in the Non-Equilibrium Thermodynamics Laboratory where he is researching electric field development in pulsed nanoseconds discharges with sub-nanoseconds precision.