Research

Evaluation of Design Standards, Materials, and Construction for Slip Formed Concrete Bridge Railings to Alleviate Sources of Early Age Deterioration

Slip formed concrete has been used extensively for pavements, barriers, and bridge railings since the 1960s due to its ease and speed of construction compared to cast in place concrete. However, despite decades of use, slip formed concrete deterioration persists and often exceeds that of other construction methods. Examples of spalling and horizontal cracking have been noted

in Ohio, but also Wisconsin, Michigan, Iowa, Illinois, and Oregon. This project seeks to correct a particular type of deterioration that is occurring in Ohio slip formed concrete bridge railings. A number of concrete railings have been found to have voids near the internal reinforcement, which often cause cracks to extend through to the concrete surface and allow for water intrusion, leading to corrosion. A change to the ODOT specification for bridge railings has been implemented, mandating use of a stiffer reinforcing bar, with the hopes of alleviating this issue. This project will test the impact of this reinforcement change, while additionally assessing the role of reinforcing bar bend tolerances, concrete cover depth, reinforcement configuration, and concrete mixture design on the development, or prevention of, cracks in slip formed concrete bridge railings.

This project is ongoing, with Phase 2 experimental work beginning in summer 2023.

This ODOT-supported project is conducted in collaboration with Tyler Ley and Norb Delatte (Oklahoma State), Jim Eudaily and Cherif Amer-Yahia (Resource International, Inc.) and Steve Prosek (Kokosing). MS student Gaurab Shrestha assisted with Phase 1 bridge inspections, and PhD student Mahmod Yahya will conduct the Phase 2 experimental work. More to come soon on this exciting project!

 

Unconventional Fly Ashes and their Impact on Concrete Performance

Fly ash, which is the material left over after coal is burned to produce electricity, is the second largest source of waste in the U.S., after municipal waste (general trash). The largest consumer of fly ash is the construction industry, where it is used both for concrete, as well as ground stabilization applications. Fly ash and concrete have a symbiotic relationship – concrete consumes the waste and encapsulates all the bad parts of the material (in particular the toxic heavy metals), while fly ash reacts within concrete to increase its strength and durability through the pozzolanic reaction. Fly ash also increases the sustainability of concrete, allowing us to reduce the proportion of portland cement, which is a very CO2 intensive material, and replace it with the fly ash.

However, despite these benefits, recent changes in coal power regulations, as well as declines in power generation from coal due to the availability of inexpensive natural gas, have resulted in shortages of available fly ash for the construction industry. This is despite the fact that we have millions, perhaps billions, of tons of fly ash available in wet or dry storage facilities (ponds or landfills) scattered throughout the country. This fly ash is not necessarily bad, its properties are simply unknown.

At Ohio State we are now investigating the effect of these ‘unconventional’ fly ashes on concrete performance, as well as understanding the role of fly ash properties on adsorption of air-entraining agents with the goal of enabling greater usage and consumption of impounded fly ashes, as well as mitigating the issues of fly ash shortfalls for the construction industry.

Publications:

The ASTM C618 Fly Ash Specification: Comparison with Other Specifications, Shortcomings, and Solutions

Viability of a Heterogenous Fly Ash Disposal Site for Use in Concrete

Suraneni group-led papers, in which Dr. Burris or CeMNT group members contributed:

Characterization and reactivity of size-fractionated unconventional fly ashes

Reactivity of Unconventional Fly Ashes, SCMs, and Fillers: Effects of Sulfates, Carbonates, and Temperature

Physicochemical characterization of unconventional fly ashes

Effects of unconventional fly ashes on cementitious paste properties

Strength activity index and bulk resistivity index modifications that differentiate inert and reactive materials

 

Using Bacteria to Increase Concrete Durability

One potential method of densifying concrete microstructure and preventing cracking due to freeze-thaw events could be through the introduction of bacteria into concrete. When the bacteria is exposed to air, as a result of a crack, the bacteria precipitates a filler mineral, typically a form of calcite, into the concrete. This bio-mineral fills the cracks, and additionally, has been shown to densify concrete microstructure, mitigating the negative impacts of concrete cracking, and leading to increased (tensile and compressive) strengths, reduced permeability and diffusivity, and through these mechanisms, increased concrete service life. If this method is successful and cost-effective, this could provide local public agencies with an opportunity to reduce maintenance and repair activities and the associated costs.

Publications:

Novelty in Concrete Binders in Self-Healing Cementitious Samples

Novelty in bacteria source production and concrete binders in self-healing cementitious samples

 

Topics related to Upscaling the Usage of Alternative Cements

One of the most pressing issues to understand relative to upscaling usage of alternative cements, is their resistance to degradation from environmental factors. In this study we investigated the performance of alternative binders in sulfate environments, to understand whether ACMs might outperform, or be problematic in these types of conditions. We found that, in general, ACMs show less expansion than portland cement, when subject to high sulfate environments. 

Publications:

Investigations of the Effects of Different Curing Methods on Calcium Sulfoaluminate

Water-to-cement Ratio of Calcium Sulfoaluminate Cements: Hydration, Setting Time, Strength Development, and Porosity

Role of Pore Structure on Resistance to Physical Crystallization Damage of Calcium Sulfoaluminate Belite (CSAB) Cement Blends

Influence of Set Retarding Admixtures on Calcium Sulfoaluminate Cement Hydration and Property Development

Effects of combination of retarders on calcium sulfoaluminate (CSA) cement systems

Shrinkage in Alternative Binder Systems

Performance of Alternative Binders in Sulfate Environments

Novel Alternative Cementitious Materials for Development of the Next Generation of Sustainable Transportation Infrastructure

 

Pervious Concrete for Acid Mine Drainage Remediation

As a result of America’s extensive history of mining, acid mine drainage (AMD) is a significant problem in many states, with over 10,000 miles of impacted streams in the U.S. When iron sulphide minerals (especially pyrite) interact with moisture and oxygen, typically as a result of mining operations, acid mine drainage develops. The oxidation of sulphide minerals releases hydrogen ions into the water, lowering its pH. This, in turn, causes dissolution of heavy metal complexes and leaches elevated concentrations of these ions into the AMD, causing acute and chronic impacts to nearby surface waters.

Retrieving AMD from Dead Lake with Asst. Prof. Ryan Winston

Abatement and treatment of AMD is difficult, expensive, and complicated, since mineral reactions which lead to AMD problems continue to occur for decades to centuries after mine closure. AMD issues affect more than Ohio, with treatment costs exceeding $200 million/yr in the US and $40 billion globally. One aspect contributing to the difficulty of remediation is the considerable costs of AMD control methods: the Ohio Division of Natural Resources reports that two of the most common AMD treatment systems it uses, lime dosing and vertical flow ponding/lime or slag leach beds, amount to as much as $825,000 per site, for a treatment period of 20 years.

Pervious concrete is a type of concrete produced using a single size aggregate and a coating of cement which allows the aggregates to stick together. The large holes (void spaces) which then occur throughout the concrete’s structure allow water to flow freely through.

Although concrete looks solid and fairly smooth to the human eye, at the microscale calcium-silicate-hydrate (C-S-H), the primary binding, and strength-giving component of hydrated cement, has extremely high surface area. This high surface area allows ions to bond through van der Waals forces, as they near the cement surface.

Additionally, as a result of alkali cations (Ca2+, Na+, K+) present in the cement, water within concrete (pore solution) is very alkaline – having a pH as high as 13.5-14.

Pervious concrete with varying porosity

These two components together make concrete the perfect material to use as a filter for acid mine drainage – lowering solution pH and capturing heavy metal ions as they make contact with the cement surface. We are currently working to develop mixture designs to allow for control of flow rate of water through pervious concrete, so that we can mirror the flow requirements of streams in which the pervious concrete will be placed, and to understand the mechanisms controlling pH reduction and contaminant removal by pervious concrete.

In September 2019, Dr. Burris and Dr. Ryan Winston, AMD Project collaborator, presented on this research to the Women & Philanthropy organization, a group of philanthropic women from very diverse backgrounds. Before the research presentation, W&P event attendees were able to interact with students, learn about Dr. Winston’s work with pervious concrete to control water infiltration and make their own sample of pervious concrete, with the help of Dr. Burris’ students.

In June 2020 our group was generously awarded funding from the Women & Philanthropy group in order to pursue additional research on pervious filters. Over the summer of 2020 several students, including Finn Haugh, Alec Grimm, and Jake Bertemes, cast and tested the durability, clogging potential, and capacity of the pervious filters for pollution removal. Thanks to their hard work a publication on our findings is forthcoming!

 

Ultra-lightweight Concrete for Floating Concrete Vessels 

Nutrient overloads in our watersheds, from agricultural runoff, have led to the development of dangerous algal blooms in lakes throughout Ohio, most famously, Lake Erie. We are working with Jake Boswell, Assistant Professor of Landscape Architecture in the Knowlton School, Nan Hu, Assistant Professor of Civil Engineering, and Rachel Gabor, Assistant Professor in Watershed Hydrology in the School of Environment and Natural Resources, to design and fabricate beautiful floating islands, which will also facilitate removal of nutrient overloads through their facilitation of growth of plant life.

https://ceg.osu.edu/news/2018/11/landscape-facultystudent-design-collaboration-leads-possible-patent

https://knowlton.osu.edu/news/2018/10/landscape-facultystudent-design-collaboration-leads-possible-patent?utm_campaign=UMAR%20onCampus%20Today%2020181121&utm_medium=email&utm_source=EOACLK

 

 

 

 

 

 

 

 

 

Increasing the Reactivity of Natural Zeolites through Pretreatment Methods

The supply high-quality fly ash meeting ASTM C 618 requirements has decreased significantly over the past decade with the shift in energy to natural gas, as well as ever-increasing rigor of environmental regulations. Natural zeolite may be a viable alternative when supplies of other supplementary cementitious materials are unavailable or unreliable. The following studies explored the effect of treating natural zeolites through milling and acid-washing, in an attempt to increase their reactivity.

Publications:

Effect of calcination on the reactivity of natural clinoptilolite zeolites used as supplementary cementitious materials

Milling as a Pretreatment Method for Increasing the Reactivity of Natural Zeolites Used as Supplementary Cementitious Materials

The Effect of Acid Treatment on the Reactivity of Natural Zeolites Used as Supplementary Cementitious Materials